1292296-62-8

Basic information

• Product Name: C₁₇H₁₆F₃NOS
• Synonyms: C₁₇H₁₆F₃NOS
• CAS NO: 1292296-62-8
• Molecular Weight: 339.381
• Mol File: 1292296-62-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₇H₁₆F₃NOS(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₇H₁₆F₃NOS(1292296-62-8)
• EPA Substance Registry System: C₁₇H₁₆F₃NOS(1292296-62-8)

Safety Data

• Hazardous Substances Data: 1292296-62-8(Hazardous Substances Data)

Upstream product

• 100-61-8 N-methylaniline 
• 349-76-8 3'-(trifluoromethyl)acetophenone 
• 92289-43-5 imidazole-1-carboxylic acid methylphenylamide 
• 454-91-1 (S)-1-(3-trifluoromethylphenyl)ethanol 
• 1292296-28-6 thioacetic acid S-[(R)-1-(3-trifluoromethylphenyl)ethyl] ester 

Downstream Products

• 1292296-73-1 methylthiocarbamic acid (S)-1-phenyl-1-(3-trifluoromethylphenyl)ethyl ester 

Relevant articles and documents

Enantioselective synthesis of tertiary thiols by intramolecular arylation of lithiated thiocarbamates

Lithiation of N-aryl S-α-alkylbenzyl thiocarbamates leads to rearrangement with migration of the N-aryl ring to the anionic centre α to S, a process which generally proceeds with ca. 98% retention of stereochemistry and returns chiral benzylic tertiary thiols in high enantiomeric ratios.