1292302-52-3

Basic information

• Product Name: 2-trifluoromethoxy-9-[(4-methylphenyl)sulfonylamino]fluorene
• Synonyms: 2-trifluoromethoxy-9-[(4-methylphenyl)sulfonylamino]fluorene
• CAS NO: 1292302-52-3
• Molecular Weight: 419.424
• Mol File: 1292302-52-3.mol

Chemical Properties

• CAS DataBase Reference: 2-trifluoromethoxy-9-[(4-methylphenyl)sulfonylamino]fluorene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-trifluoromethoxy-9-[(4-methylphenyl)sulfonylamino]fluorene(1292302-52-3)
• EPA Substance Registry System: 2-trifluoromethoxy-9-[(4-methylphenyl)sulfonylamino]fluorene(1292302-52-3)

Safety Data

• Hazardous Substances Data: 1292302-52-3(Hazardous Substances Data)

Upstream product

• 139301-27-2 4-trifluoromethoxyphenylboronic acid 
• 728919-13-9 4'-(trifluoromethoxy)-[1,1'-biphenyl]-2-carbaldehyde 
• 70-55-3 toluene-4-sulfonamide 

Relevant articles and documents

Facile Cu(OTf)2-catalyzed preparation of 9-tosylaminofluorene derivatives from o-arylated N-tosylbenzaldimines

The 9-tosylaminofluorene derivatives were synthesized conveniently by Cu(OTf)2-catalyzed aza-Friedel-Crafts reaction of o-arylated N-tosylbenzaldimines in high yields. This is an efficient, atom-economic, and green method.

Efficient synthesis of 9-tosylaminofluorene derivatives by boron trifluoride etherate-catalyzed aza-friedel-crafts reaction of in situ generated N-tosylbenzaldimines

An efficient and expeditious boron trifluoride etherate (BF 3·Et2O) catalyzed one-pot reaction for the synthesis of N-tosyl-9-aminofluorenes and anthracene derivatives from in situ generated N-tosylbenzaldimines via an aza-Friedal-Crafts reaction has been developed. The catalytic reaction shows high substrate tolerance with excellent yields.