1292309-35-3Relevant academic research and scientific papers
Spiro indane-based phosphine-oxazolines as highly efficient P,N ligands for enantioselective Pd-catalyzed allylic alkylation of indoles and allylic etherification
Qiu, Zhongxuan,Sun, Rui,Yang, Kun,Teng, Dawei
, (2019)
A series of indane-based phosphine-oxazoline ligands with a spirocarbon stereogenic center were examined for palladium-catalyzed asymmetric allylic alkylation of indoles. Under optimized conditions, high yields (up to 98%) and enantioselectivities (up to
Chiral N-1-adamantyl-N-trans-cinnamylaniline type ligands: Synthesis and application to palladium-catalyzed asymmetric allylic alkylation of indoles
Mino, Takashi,Nishikawa, Kenji,Asano, Moeko,Shima, Yamato,Ebisawa, Toshibumi,Yoshida, Yasushi,Sakamoto, Masami
, p. 7509 - 7519 (2016/08/16)
Such chiral phosphine-internal olefin hybrid type ligands as N-1-adamantyl-N-cinnamylaniline derivatives 1 with C(aryl)-N(amine) bond axial chirality were synthesized and utilized for the palladium-catalyzed asymmetric allylic alkylation of indoles to aff
Palladium-catalyzed asymmetric allylic alkylation of indoles by C-N bond axially chiral phosphine ligands
Mino, Takashi,Ishikawa, Miho,Nishikawa, Kenji,Wakui, Kazuya,Sakamoto, Masami
, p. 499 - 504 (2013/06/27)
Abstract The palladium-catalyzed asymmetric allylic alkylation of indoles with 1,3-diphenyl-2-propenyl acetate using P/N-type ligands such as N-aryl indole, C-N bond axially chiral aminophosphine (aS)-L4, gave the desired products 1 in good yields and wit
