129266-49-5Relevant academic research and scientific papers
Cross-Couplings of Alkyl Electrophiles under Ligandless Conditions: Negishi Reactions of Organozirconium Reagents
Wiskur, Sheryl L.,Korte, Alexander,Fu, Gregory C.
, p. 82 - 83 (2004)
This report establishes that simple, ligandless palladium complexes can catalyze the first zirconium-Negishi reactions of alkyl electrophiles. In view of the attractiveness of ligandless catalysts (cost, simplicity, and ease of purification), these observations add a significant and intriguing new dimension to the development of effective palladium-based processes for coupling alkyl electrophiles. Copyright
