1292810-18-4Relevant academic research and scientific papers
Catalytic enantioselective ring-opening reaction of meso-aziridines with α-isothiocyanato imides
Cao, Yi-Ming,Zhang, Fu-Ting,Shen, Fang-Fang,Wang, Rui
, p. 9476 - 9480 (2013)
Open up your chemistry! By using cinchonine-based trimeric quaternary ammonium salts as catalysts, meso-aziridines can be ring-opened, in an enantioselective manner, through nucleophilic addition of the sulfur atom of α-isothiocyanato imides (see scheme;
Guanidine-catalyzed enantioselective desymmetrization of meso-aziridines
Zhang, Yan,Kee, Choon Wee,Lee, Richmond,Fu, Xiao,Soh, Julian Ying-Teck,Loh, Esther Mun Foong,Huang, Kuo-Wei,Tan, Choon-Hong
supporting information; experimental part, p. 3897 - 3899 (2011/05/04)
An amino-indanol derived chiral guanidine was developed as an efficient Bronsted base catalyst for the desymmetrization of meso-aziridines with both thiols and carbamodithioic acids as nucleophiles, which provided 1,2-difunctionalized ring-opened products
