1292811-33-6

Upstream product

• 1227673-16-6 (2R,3S)-2-methyl-3-(t-butyldimethylsilyloxy)-5-phenylpentanal 
• 804559-38-4 (R,R)-crotylsilane 
• 69611-01-4 (Z)-2-(but-2-enyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 

Relevant academic research and scientific papers

COMPOSITIONS AND METHODS FOR STEREOSELECTIVE ALDEHYDE ALLYLATION AND CROTYLATION

Compositions and methods for practical, stereoselective allylation and crotylation for aldehyde substrates are described. The compositions and methods comprise reagents for allylation and/or crotylation and acids. In some embodiments, the reagents and acids are pre-mixed.

A more comprehensive and highly practical solution to enantioselective aldehyde crotylation

The enantioselective crotylation of aldehydes with 1,2- diaminochlorocrotylsilane reagents is effectively catalyzed by Sc(OTf) 3. The one significant limitation on the utility of these reagents-substrate scope-has thus been addressed. The net r