1292834-38-8Relevant academic research and scientific papers
Pi complex of phosphaphenylmolybdenum as well as preparation method and application thereof
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, (2020/07/28)
The invention discloses a pi complex of phosphaphenyl molybdenum as well as a preparation method and application of the pi complex. The structural formula of the complex is shown in the specification.The preparation method of the complex comprises the fol
A phosphinine 2-carboxaldehyde
Mao, Yanli,Mathey, Francois
, p. 1162 - 1163 (2012/03/27)
The first phosphinine 2-carboxaldehyde was synthesized as shown and transformed into an alkene via a Wittig reaction without destruction of the phosphinine ring.
Investigating the phospholylcarbene to phosphinine conversion
Chen, Hui,Li, Jin,Wang, Huaiqiu,Liu, Hui,Duan, Zheng,Mathey, Franaois
, p. 1540 - 1543 (2011/06/22)
A DFT study suggests that the conversion of arsolylcarbenes into arsenines as described by Maerkl proceeds via arsabenzvalenes. A similar conversion does not work with phospholylcarbenes. However, we have found that, in some cases, 1-diazoalkylphosphole s
