1292847-91-6

Upstream product

• 10273-89-9 2-(2-methylphenyl)pyridine 
• 17264-74-3 sodium 2-chlorobenzoate 
• 16419-60-6 2-Methylphenylboronic acid 
• 609-65-4 o-chlorobenzoyl chloride 
• 109-04-6 2-bromo-pyridine 

Relevant academic research and scientific papers

Copper(II)-catalyzed ortho-benzoxylation of 2-arylpyridines with sodium carboxylates

Copper-catalyzed ortho-benzoxylation of an sp2 CH bond by sodium carboxylates is described. The procedure tolerates carbomethoxy, formyl, bromo, and chloro groups, providing the benzoxylated products in moderate to good yields.

Copper(II)-catalyzed ortho-functionalization of 2-arylpyridines with acyl chlorides

Copper-catalyzed ortho-benzoxylation of 2-arylpyridine sp2 C-H bonds with acyl chloride is described. Notably, switching the base from t-BuOK to Li2CO3 causes chlorination of the C-H bond to take place. The Royal Society of Chemistry.