129287-79-2

Upstream product

• 129287-61-2 (1'S,2R,5R,6R)-2-tert-Butyl-6-methyl-5-(1'-phenylethyl)-1,3-dioxan-4-on 

Downstream Products

• 1441-20-9 (R)-(-)-3-phenylbutyric acid methyl ester 

Relevant academic research and scientific papers

(E,R,R)-5-Alkylidene-2-tert-butyl-6-methyl-1,3-dioxan-4-ones: Preparation from (R)-3-Hydroxybutbutyric Acid, Cuprate Additions and Hydrolyses to 3-Hydroxycarboxylic Acids with Chiral Secondary Alkyl Substituents in the 2-Position

Li enolates of (R,R)-2-tert-Butyl-6-methyl-1,3-dioxan-4-one add to aliphatic or aromatic aldehydes with relative topicity Re,Re (2:1 to 10:1, 9 examples).The title compounds are obtained from these aldol adducts by dehydration through mesylates (5 example