1293384-41-4

Basic information

• Product Name: methyl 3-methoxy-4-(2,3,4,6-tetra-O-acetyl-β-D-allopyranosyloxy)benzoate
• Synonyms: methyl 3-methoxy-4-(2,3,4,6-tetra-O-acetyl-β-D-allopyranosyloxy)benzoate
• CAS NO: 1293384-41-4
• Molecular Weight: 512.468
• Mol File: 1293384-41-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 3-methoxy-4-(2,3,4,6-tetra-O-acetyl-β-D-allopyranosyloxy)benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3-methoxy-4-(2,3,4,6-tetra-O-acetyl-β-D-allopyranosyloxy)benzoate(1293384-41-4)
• EPA Substance Registry System: methyl 3-methoxy-4-(2,3,4,6-tetra-O-acetyl-β-D-allopyranosyloxy)benzoate(1293384-41-4)

Safety Data

• Hazardous Substances Data: 1293384-41-4(Hazardous Substances Data)

Upstream product

• 144071-49-8 1,2,3,4,6-penta-O-acetyl-D-allopyranose 
• 3943-74-6 4-hydroxy-3-methoxybenzoic acid methyl ester 
• 1293384-39-0 2,3,4,6-tetra-O-acetyl-D-allopyranosyl N-phenyltrifluoroacetimidate 

Downstream Products

• 1293384-43-6 methyl 3-methoxy-4-(β-D-allopyranosyloxy)benzoate 
• 1293384-45-8 methyl 3-methoxy-4-(2',3',4'-tri-O-benzyl-6'-O-trityl-β-D-allopyranosyloxy)benzoate 
• 1293384-47-0 3-methoxy-4-(2',3',4'-tri-O-benzyl-6'-O-trityl-β-D-allopyranosyloxy)benzoic acid 

Relevant articles and documents

Synthesis of oligomeric 4-(glycosyloxy)benzoate macrocyclic glycosides

Clemoarmanoside A and Clemahexapetoside A, two novel cyclic dimers of 4-(glycosyloxy)benzoates containing the unusual d-allopyranose as one of the sugar units, were synthesized for the first time. The convenient synthetic approach was adapted to the assembly of the symmetrical trimeric, tetrameric, and pentameric congeners. The synthesis clarified the discrepancy in the NMR data reported for the natural products. X-ray diffraction analysis of Clemahexapetoside A revealed that it adopted an armchair conformation with two carbohydrate rings as the arms and two aromatic rings as the back and seat, respectively.