1293397-72-4Relevant academic research and scientific papers
Synthesis of ms- and β-substituted ruthenium(II) porphyrinates
Chizhova,Kumeev,Mamardashvili, N. Zh.
, p. 1421 - 1424 (2010)
The reactions of 5,10,15,20-tetraphenylporphine, 2,3,7,8,12,13,17,18- octaethylporphine, and tetra(4-methoxyphenyl)porphine with Ru 3(CO)12 in boiling phenol were studied by spectrophotometry. The following compounds were synthesized and identified: Ru2+(CO)(H2O) 5,10,15,20-tetraphenylporphyrinate, Ru 2+(CO)(H2O) 2,3,7,8,12,13,17,18-octaethylporphyrinate, Ru2+(CO)(Py) 2,3,7,8,12,13,17,18-octaethylporphyrinate, and Ru 2+(CO)(H2O) tetra(4-methoxyphenyl)porphyrinate. The strong electronic effect of the substituents on the reactivity of the tetrapyrrole cycle during the formation of the corresponding porphyrinates was established.
