1293409-75-2Relevant academic research and scientific papers
Synthesis, characterization and application of pincer-type nickel iminophosphinite complexes
Sanford, Jessica,Dent, Catlin,Masuda, Jason D.,Xia, Aibing
, p. 1091 - 1094 (2011/05/04)
Two pincer-type nickel iminophosphinite complexes, [(2-(CHNR)-6- (OPR′2)C6H3)NiCl] (R = 2,6- iPr2C6H3, R′ = Ph (2a) or iPr (2b)), were synthesized from the reactions of bis(1,5-cyclooctadiene)nickel(0) and corresponding iminophosphinite ligands. The solid state structures of the nickel pincer complexes were determined by X-ray single crystal diffraction studies. They were successfully employed in the Kumada reaction of non-activated aryl chlorides and phenylmagnesium bromide at room temperature.
