129357-94-4

Basic information

• Product Name: 2-bromo-2-chloro-1,1,1-trifluoroethyl radical
• CAS NO: 129357-94-4
• Molecular Weight: 196.374
• Mol File: 129357-94-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-bromo-2-chloro-1,1,1-trifluoroethyl radical(CAS DataBase Reference)
• NIST Chemistry Reference: 2-bromo-2-chloro-1,1,1-trifluoroethyl radical(129357-94-4)
• EPA Substance Registry System: 2-bromo-2-chloro-1,1,1-trifluoroethyl radical(129357-94-4)

Safety Data

• Hazardous Substances Data: 129357-94-4(Hazardous Substances Data)

Upstream product

• 151-67-7 1,1,1-trifluoro-2-bromo-2-chloroethane 

Relevant articles and documents

Electron Transfer Reactions of Halothane-derived Peroxyl Free Radicals, CF3CHClO2.: Measurement of Absolute Rate Constants by Pulse Radiolysis

The halothane-derived peroxyl radical CF3CHClO2. has been generated in aqueous solutions by pulse radiolysis.Absolute rate constants for the reduction of halothane (2-bromo-2-chloro-1,1,1-trifluoroethane) by hydrated electrons, hydrogen atoms, and propan-2-ol free radicals have been determined to be k 1.4E10, 3.8E8, and 7.6E7 l mol-1 s-1, respectively.The predominant product radical CF3CHCl rapidly adds O2, and an estimate of k 1.3E9 l mol-1 s-1, has been obtained for the absolute rate constant of this reaction.The resulting peroxyl radical CF3CHClO2. has been found to react rapidly with a variety of nucleophilic compounds such as 2,2'-azinobis(3-ethylbenzthiazoline-6-sulphonate), the phenothiazines promethazine, chlorpromazine, and metiazinic acid, the vitamins C and E, and propyl gallate.The absolute rate constants for these reactions are found to be generally lower than for corresponding reactions of the carbon tetrachloride-derived radical, CCl3O2..