1293932-58-7Relevant academic research and scientific papers
Cyclic alumosiloxanes and alumosilicates: Exemplifying the loewenstein rule at the molecular level
Gonzalez-Gallardo, Sandra,Jancik, Vojtech,Delgado-Robles, Alma A.,Moya-Cabrera, Monica
, p. 4226 - 4228 (2011)
The cyclic alumosiloxane [{LAl(μ-O)(Ph2Si)(μ-O)} 2] (3) and alumosilicate [{LAl(μ-O){(tBuO) 2Si}(μ-O)}2] (4) were obtained by reaction of the appropriate R2Si(OH)2 precursor (R = Ph, OtBu) with [{LAl(H)}2(μ-O)] (1), providing a nice illustration of the Loewenstein rule at work at the molecular level.
