129529-31-3

Basic information

• Product Name: diisopropyl 2-hydroxyphenylphosphonate
• Synonyms: diisopropyl 2-hydroxyphenylphosphonate
• CAS NO: 129529-31-3
• Molecular Weight: 258.254
• Mol File: 129529-31-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: diisopropyl 2-hydroxyphenylphosphonate(CAS DataBase Reference)
• NIST Chemistry Reference: diisopropyl 2-hydroxyphenylphosphonate(129529-31-3)
• EPA Substance Registry System: diisopropyl 2-hydroxyphenylphosphonate(129529-31-3)

Safety Data

• Hazardous Substances Data: 129529-31-3(Hazardous Substances Data)

Upstream product

• 51496-03-8 diisopropyl phenyl phosphate 
• 5076-68-6 diethyl 4-methoxyphenyl phosphate 
• 1809-20-7 diisopropyl hydrogenphosphonate 
• 95-56-7 2-hydroxybromobenzene 
• 533-58-4 2-Iodophenol 

Relevant articles and documents

Stereoselective synthesis of phosphoryl-substituted phenols

Copper-catalyzed C-X activation-phosphorylation of aryls bearing different groups has been achieved using P(O)-H compounds as efficient phosphorylation reagents without the assistance of any ligand. Optically active H-phosphinates can also act as good substrates in the reaction, giving the (Sp)-phosphoryl substituted phenolic compounds stereospecifically with retention of configuration at the phosphorus center. Furthermore, it is shown that the migration of phosphorus on O-aryl phosphonates from oxygen to carbon also proceeds stereospecifically to produce the corresponding optically active (Rp)-phosphoryl-substituted phenolic compounds with retention of configuration at phosphorus via treatment with lithium diisopropylamide (LDA). Plausible mechanisms have been proposed for these reactions.