129547-68-8Relevant academic research and scientific papers
Oligomerization of acrylic acid derivatives by a reaction with the alkylcopper(I)phosphine complex
Mitani, Michiharu,Pakjamsai, Chitsakon,Tsuchida, Teruko,Kudoh, Hidekazu
, p. 112 - 128 (2007/10/03)
Reaction of alkylcopper(I)phosphine complexes with electron-deficient olefins effected preferentially the products based on oligomerization, e.g. the product obtained by sequential conjugated addition, trimerization and cyclization from methyl methacrylate and the dimerization product from butyl acrylate.
Chromium(II)-Mediated Intermolecular Free-Radical Carbon-Carbon Bond Formation
Tashtoush, Hasan I.,Sustmann, Reiner
, p. 287 - 289 (2007/10/02)
Chromium(II) complexes are found to be effective mediators for intermolecular free-radical C-C bond formation.Thus, Cr(en)2(2+) species react with alkyl halides to generate the corresponding alkyl radicals which are readily trapped with electron-deficient alkenes to afford the coupling products.Key Words: Radicals / Bond formation, C-C / Chromium(II) complexes
