129548-52-3Relevant academic research and scientific papers
Reduction of Allylic Nitro Compounds to Oximes with Carbon Disulfide under Solid-Liquid Phase-Transfer Catalysis Conditions
Albanese, Domenico,Landini, Dario,Penso, Michele
, p. 333 - 336 (2007/10/02)
A mild procedure for the synthesis of allylic oximes 2 from the corresponding nitro derivatives 1, using carbon disulfide as reducting agent in the presence of wet potassium carbonate and a catalytic amount of a phase-transfer agent, is described.
One-pot Conversion of Allylic Nitro Compounds Into Nitriles with Carbon Disulphide under Phase-transfer Catalysis Conditions
Albanese, Domenico,Landini, Dario,Penso, Michele,Pozzi, Gianluca
, p. 965 - 971 (2007/10/02)
An one-pot synthesis of allylic nitriles 3 from the corresponding nitro derivatives 1 is described.In the first step the substrates 1 are reduced to the oximes 2 by carbon disulphide in the presence of wet potassium carbonate, in solid-liquid PTC conditions.In the second, the formed oximes 2 are dehydrated by adding more CS2 and 15percent aqueous NaOH.
