1295502-63-4Relevant academic research and scientific papers
Utilization of Donor–Acceptor Interactions for the Catalytic Acceleration of Nucleophilic Additions to Aromatic Carbonyl Compounds
Uchikura, Tatsuhiro,Ono, Kosuke,Takahashi, Kohei,Iwasawa, Nobuharu
, p. 2130 - 2133 (2018)
A conceptually new method for the catalytic electrophilic activation of aromatic carbonyl substrates, by utilizing donor–acceptor interactions between an electron-deficient macrocyclic boronic ester host ([2+2]BTH-F) and an aromatic carbonyl guest substrate, was realized. In the presence of a catalytic amount of [2+2]BTH-F, dramatic acceleration of the nucleophilic addition of a ketene silyl acetal towards either electron-rich aromatic aldehydes or ketones was achieved. Several control experiments confirmed that inclusion of the aromatic substrates within [2+2]BTH-F, through efficient donor–acceptor interactions, is essential for the acceleration of the reaction.
Boron compound
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Paragraph 0103, (2017/08/23)
PROBLEM TO BE SOLVED: To provide a method for producing a boron compound represented by a formula (II) from a compound represented by a formula (I) in a short reaction time with good yield.SOLUTION: There is provided a method for producing a boron compound represented by a formula (II), the method comprising: a step of producing a first intermediate obtained by reacting a compound represented by a formula (I) and a lithium amide compound or an alkyllithium compound and a second intermediate from the first intermediate; and a step of reacting the second intermediate and an alcohol or a divalent carboxylic acid. (I) (II) [Y represents a divalent group; and Y represents a boric acid ester residue.]
POLYMER COMPOUND
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Paragraph 0238; 0239, (2016/10/07)
The invention relates to a polymer compound. A photoelectric conversion device that contains the polymer compound having a structural unit represented by formula (1) has high photoelectric conversion efficiency. (wherein, X1 and X2 are the same or different and represent a nitrogen atom or -CH-. Y1 represents a sulfur atom, an oxygen atom, a selenium atom, -N(R1)- or -CR2-CR3-. R1, R2 and R3 are the same or different and represent a hydrogen atom or a substituent. W1 represents a cyano group, a monovalent organic group having a fluorine atom or a halogen atom. W2 represents a cyano group, a monovalent organic group having a fluorine atom, a halogen atom or a hydrogen atom.
Compound used for forming high-molecular compound
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Paragraph 0812; 0813; 0814; 0815; 0816; 0817; 0818, (2016/10/08)
The present invention provides a macromolecular compound by which the short-circuit current density and the photoelectric conversion efficiency are enhanced when the macromolecular compound is used in an organic layer contained in a photovoltaic cell. Specifically, the present invention provides a macromolecular compound having a structural unit represented by Formula (5): wherein R52 and R53 are the same as or different from each other and represent hydrogen atoms, halogen atoms, alkyl groups, alkyl oxygen radicals, alkyl sulfonium, aryl groups, aryl oxygen radicals, aryl sulfonium, aryl alkyl, aryl alkyl oxygen radicals, acyl groups, acyloxy, acylamino, imide groups, amidogen, substituted amino, substituted silicyl, substituted silicon alkyl oxygen radicals, substituted silicon alkyl harvard, silicon alkyl amine, univalent heterocyclic radical, heterocyclic oxygen radicals, heterocyclic sulfonium, aryl alkenyl, aryl alkynyl, carboxyl or cyan; W1 and W2 are the same as or different from each other and represent hydrogen atoms, halogen atoms, alkyl sulfonate base, aryl sulfonic acid ester base, aryl alkyl sulfonate base, boric acid ester residues, matte methyl, scales base, Phosphonic acid ester methyl, single halogenated methyl, boric acid residues, formyl groups, vinyl or organic tin residues.
METHOD FOR MANUFACTURING BORON COMPOUND
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Paragraph 0083, (2018/10/31)
PROBLEM TO BE SOLVED: To provide a method for manufacturing a boron compound represented by the formula (II) from a compound represented by the formula (I) as a monomer providing a repeating unit of a polymer compound used for an organic thin film solar cell at a good yield. SOLUTION: There is provided a method for manufacturing a boron compound represented by the formula (II) by reacting a compound represented by the formula (I), a diboric acid ester derivative and a metal catalyst. In the formulae (I) and (II), Y represents a bivalent group, Y in both formulae are the same, and W1 and W2 represent each independently a boric acid ester residue. COPYRIGHT: (C)2015,JPOandINPIT
