129574-48-7Relevant articles and documents
Photochemistry of Halogenocarbon Compounds. Part 5. Photolysis of Fluorinated 1,2,3-Triazine Derivatives
Chambers, Richard D.,Shepherd, Thomas,Tamura, Masayuki
, p. 975 - 981 (2007/10/02)
Photolysis experiments are described on perfluoro-1,2,3-triazine (9) and its corresponding perfluoroisopropyl derivatives.A polymer was obtained from (9) but a dimer of perfluoro-2,4-di-isopropylazete (16) is obtained, from (15) quantitatively.The endo structure of the dimer is revealed by formation of a stable carbanion on addition of CsF.Trapping of the azete (16) with furan gave interconvertible 1:1 cycloaddition products.Products consistent with co-dimerisation of azetes are described.