129579-12-0Relevant academic research and scientific papers
REACTION OF INTERNAL PERFLUORINATED α-OXIDES WITH AMMONIA
Saloutina, L. V.,Zapevalov, A. Ya.,Kodess, M. I.,Kolenko, I. P.
, p. 628 - 634 (2007/10/02)
The action of ammonia leads to nucleophilic opening of the epoxide ring in internal perfluorinated α oxides with the formation of aminoiminoperfluoroalkanols and their dissociation products.In unsymmetrical disubstituted 2,3-epoxyperfluoroalkanes attack by ammonia at the carbon atoms of the epoxide ring is not regioselective, whereas in the trisubstituted compounds regiospecific reaction with ammonia occurs.The stability of the internal perfluorinated α-oxides to the action of ammonia is increased with increase in the size of the fluoroalkyl substituents.
