129600-91-5Relevant academic research and scientific papers
Fluorination of sulfides using IF5-Et3N-3HF
Ayuba, Shinichi,Yoneda, Norihiko,Fukuhara, Tsuyoshi,Hara, Shoji
, p. 1597 - 1603 (2007/10/03)
Mono- and difluorinations of sulfides were achieved using a novel fluorinating reagent, IF5-Et3N-3HF. The reagent is applicable for substrates having various electron-withdrawing groups, such as an ester, amide, ketone, ni
Electrochemistry of Hypervalent Compounds. 6. Selective α-Fluorination of Sulfides Using Electrogenerated Hypervalent p-Methoxyiodobenzene Difluoride
Fuchigami, Toshio,Fujita, Toshiyasu,Higashiya, Seiichiro,Konno, Akinori
, p. 131 - 133 (2007/10/03)
Anodically generated hypervalent p-methoxyiodobenezene difluoride reacted with α-(arylthio)- and α-(benzylthio)acetates, and α-(phenylthio)acetophenone to provide the corresponding fluorinated compounds. In all cases, a fluorine atom was introduced exclus
Electrolytic Partial Fluorination of Organic Compounds. 17. Regiospecific Anodic Fluorination of Sulfides Bearing Electron-Withdrawing Substituents at the Position α to the Sulfur Atom
Fuchigami, Toshio,Shimojo, Moriyasu,Konno, Akinori
, p. 3459 - 3464 (2007/10/02)
Regiospecific monofluorination of various sulfides bearing electron-withdrawing substituents, cyano, ester, acyl, amino, and phosphonate groups, at their α-positions was successfully carried out by the anodic oxidation of the sulfides in Et3N*3HF/MeCN usi
Ethyl phenylsulfinyl fluoroacetate, a new and versatile reagent for the preparation of α-fluoro-α,β-unsaturated carboxylic acid esters
Allmendinger, Thomas
, p. 4905 - 4914 (2007/10/02)
The title compound 2 can be alkylated with a wide range of alkyl halides and Michael acceptors. Subsequent thermal elimination of phenyl sulfinic acid 3 leads to α-fluoro-α,β-unsaturated ethyl carboxylates 5 and 10, an important class of intermediates for fluorine containing biologically active compounds.
