1296306-84-7Relevant academic research and scientific papers
Transfer of organic groups to gold using organotin compounds
Meyer, Nadine,Sivanathan, Sivatharushan,Mohr, Fabian
, p. 1244 - 1247 (2011)
PhSnMe3 undergoes transmetallation with [AuCl(EPh3)] (E = P, As) in refluxing toluene forming [AuPh(EPh3)] and Me 3SnCl. The analogous nBu derivative does not transmetallate, even under forcing conditions. Similarly, 1-(trimethylstannyl) naphthalene and 1-(trimethylstannyl)-8-iodonaphthalene react with [AuCl(PPh 3)] to give good yields of the corresponding naphthylgold(I) complexes which were spectroscopically and structurally characterised.
