129762-11-4Relevant academic research and scientific papers
Disulfidation of Alkynes and Alkenes with Gallium Trichloride
Usugi, Shin-Ichi,Yorimitsu, Hideki,Shinokubo, Hiroshi,Oshima, Koichiro
, p. 601 - 603 (2004)
(Matrix presented) Treatment of diphenyl disulfide and terminal alkynes with gallium trichloride afforded (E)-1,2-diphenylthio-1-alkenes selectively (E/Z > 20/1). Alkenes also underwent this reaction to form trans adducts.
Boron Trifluoride-promoted Reaction of 4'-Nitrobenzenesulphenanilide with Alkynes. Formal Addition of Benzenesulphenyl Fluoride to Carbon-Carbon Triple Bonds
Benati, Luisa,Montevecchi, P. Carlo,Spagnolo, Piero
, p. 1690 - 1695 (2007/10/02)
The BF3-promoted reaction of 4'-nitrobenzenesulphenanilide with simple alkyl- and aryl-alkynes at 80 deg C in the presence of tetrabutylammonium tetrafluoroborate provides a one-pot synthetic route to β-fluorovinyl sulphides via a formal regioselective and trans-stereospecific addition of benzenesulphenyl fluoride towards carbon-carbon triple bonds.
