129806-69-5Relevant articles and documents
Enantioconvergent Cross-Couplings of Alkyl Electrophiles: The Catalytic Asymmetric Synthesis of Organosilanes
Schwarzwalder, Gregg M.,Matier, Carson D.,Fu, Gregory C.
supporting information, p. 3571 - 3574 (2019/02/13)
Metal-catalyzed enantioconvergent cross-coupling reactions of alkyl electrophiles are emerging as a powerful tool in asymmetric synthesis. To date, high enantioselectivity has been limited to couplings of electrophiles that bear a directing group or a pro
Intermolecular Schmidt reaction of alkyl azides with acyl silanes
Yu, Chun-Jiao,Li, Rui,Gu, Peiming
, p. 3568 - 3570 (2016/07/18)
The first intermolecular Schmidt reaction of alkyl azides with acyl silanes has been designed and realized, producing a range of amides with absolute site selectivity in good to excellent yields. The mechanism of the conversion has been proposed, and the reaction exhibits scope of substrates.