1298063-76-9

Upstream product

• 869162-67-4 (5S)-6-hydroxy-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enone 
• 1298063-04-3 (2E,5S)-2-methyl-5-(prop-1-en-2-yl)hex-2-enedial 
• 869168-74-1 (6S)-3-methyl-6-(prop-1-en-2-yl)cyclohex-3-ene-1,2-diol 
• 1298063-18-9 (2E,5S)-2-methyl-5-(prop-1-en-2-yl)hex-2-ene-1,6-diyl diacetate 
• 1298063-07-6 (2E,5S)-2-methyl-5-(prop-1-en-2-yl)hex-2-ene-1,6-diol 
• 98-59-9 p-toluenesulfonyl chloride 

Relevant academic research and scientific papers

Selective deoxygenation of allylic alcohol: Stereocontrolled synthesis of lavandulol

Selective deoxygenation of allylic alcohol can be successfully carried out by the formation of alkoxyalkyl ether (EE or MOM), followed by Pd(dppe)Cl 2-catalyzed reduction with LiBHEt3. (+)-S-Lavandulol has been efficiently synthesized by the application of this protocol to the diol derived from the Pb(OAc)4-promoted oxidative ring-opening of (-)-R-carvone. This deoxygenation method is general and selective for allylic alcohols.