129817-41-0Relevant academic research and scientific papers
Iridium(I), -(III), and -(V) Complexes of an O-Donor Ligand in Alkyne Hydrosilylation
Tanke, Robin S.,Crabtree, Robert H.
, p. 1056 - 1057 (1990)
The O-donor ligand C(PH2PO)3(1-) (triso) stabilises iridium-(I), -(III), and -(V) species such as ; the complexes catalyse the net anti-addition of silanes to alkynes.
Unusual activity and selectivity in alkyne hydrosilylation with an indium catalyst stabilized by an O-donor ligand
Tanke, Robin S.,Crabtree, Robert H.
, p. 7984 - 7989 (2007/10/02)
Catalytic alkyne hydrosilylation has been found for iridium in the O-donor ligand environment of Grim's triso ligand (=tris(diphenyloxophosphoranyl)methanide). The reaction is selective for 1-alkynes and regioselective for β-products and gives the thermod
