129829-53-4

Basic information

• Product Name: (+)-(1R,4R,5R,6R)-2,2-bis(benzyloxy)-5,6-exo-epoxy-7-oxabicyclo<2.2.1>heptane
• Synonyms: (+)-(1R,4R,5R,6R)-2,2-bis(benzyloxy)-5,6-exo-epoxy-7-oxabicyclo<2.2.1>heptane
• CAS NO: 129829-53-4
• Molecular Weight: 324.376
• Mol File: 129829-53-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (+)-(1R,4R,5R,6R)-2,2-bis(benzyloxy)-5,6-exo-epoxy-7-oxabicyclo<2.2.1>heptane(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-(1R,4R,5R,6R)-2,2-bis(benzyloxy)-5,6-exo-epoxy-7-oxabicyclo<2.2.1>heptane(129829-53-4)
• EPA Substance Registry System: (+)-(1R,4R,5R,6R)-2,2-bis(benzyloxy)-5,6-exo-epoxy-7-oxabicyclo<2.2.1>heptane(129829-53-4)

Safety Data

• Hazardous Substances Data: 129829-53-4(Hazardous Substances Data)

Upstream product

• 94482-74-3 (+)-(1R,2R,4R)-2-endo-cyano-7-oxabicyclo<2.2.1>hept-5-ene-2-exo-yl acetate 
• 88708-22-9 (+)-(1R,4R)-7-oxabicyclo<2.2.1>-hept-5-en-2-one 
• 14642-79-6 benzyloxy-trimethylsilane 
• 126372-05-2 (+)-(1R,4R)-5,5-bis(benzyloxy)-7-oxabicyclo<2.2.1>hept-2-ene 

Downstream Products

• 115140-20-0 (1R,4R,5R,6S)-6-Benzyloxy-5-hydroxy-7-oxa-bicyclo[2.2.1]heptan-2-one 
• 80226-74-0 (-)-(1R,2S,3S,4R)-1,2,3,4-tetraacetoxy-5-cyclohexene 
• 129745-63-7 (-)-1D-2,3,4-tris-O-<(tert-butyl)dimethylsilyl>cyclohex-2-ene-1,2,4/3-tetrol 
• 129829-58-9 (-)-1L-2,3,4-tris-O-<(tert-butyl)dimethylsilyl>cyclohex-2-ene-1,3/2,4-tetrol 
• 129829-62-5 (+)-1D-Tetra-O-acetylcyclohexane-1,2,4/3-tetrol 
• 129938-05-2 (1S,2S,3S,4R)-cyclohexane-1,2,3,4-tetrol 
• 129829-60-3 (+)-Tetra-O-acetylconduritol F 
• 526-87-4 (1R,2S,3S,4S)-5-cyclohexene-1,2,3,4-tetrol 
• 80338-90-5 (1R,2S,3S,4R)-1,2,3,4,tetrahydroxy-5-cyclohexene 
• 78147-99-6 (-)-1L-Cyclohexane-1,3/2,4-tetrol 
• 765884-92-2 (-)-(1R,2S,3S,4R)-4-aminocyclohex-5-ene-1,2,3-triol 
• 129745-62-6 (-)-(4R,5S,6R)-4,5,6-tris(<(tert-butyl)dimethylsilyl>oxy)cyclohex-2-en-1-one 
• 872976-89-1 (-)-2-((1S,4R,5S,6S)-4,5,6-tris-{[tert-butyl(dimethyl)silyl]oxy}cyclohex-2-en-1-yl)-1H-isoindole-1,3(2H)-dione 
• 861668-42-0 (-)-(1R,2S,3S,4R)-1,2,3-tris{[(tert-butyl)dimethylsilyl]oxy}-4-phthalimidocyclohex-5-ene 

Relevant articles and documents

Total Syntheses of (-)-Conduritol B ((-)-1L-Cyclohex-5-ene-1,3/2,4-tetrol) and of (+)-Conduritol F ((+)-1D-Cyclohex-5-ene-1,2,4/3-tetrol). Determination of the Absolute Configuration of (+)-Leucanthemitol

The 'naked sugar' (+)-(1R,2R,4R)-2-endo-cyano-7-oxabicyclohept-5-en-2-exo-yl acetate ((+)-4) was converted (7 steps , 45percent overall) with high stereoselectivity into (-)-(4R,5S,6R)-4,5,6-tris(oxy)cyclohex-2-en-1-one (