129832-24-2

Upstream product

• 107153-26-4 (+/-)-2exo-acetoxy-bornanoic acid-⁽¹⁰⁾ 
• 464-78-8 (1S)-ketopinic acid 
• 54371-12-9 (1S)-7,7-dimethyl-2-oxobicyclo[2.2.1]heptane-1-carbonyl chloride 
• 129800-94-8 benzyl (1S)-ketopinate 
• 464-78-8 (1S)-(+)-ketopinic acid 
• 129800-97-1 benzyl (1S,2R)-2-hydroxy-7,7-dimethylbicyclo<2.2.1>heptane-1-carboxylate 
• 129800-97-1 benzyl (1S,2S)-2-hydroxy-7,7-dimethylbicyclo<2.2.1>heptane-1-carboxylate 

Downstream Products

• 464-78-8 (+/-)-ketopinic acid 

Relevant academic research and scientific papers

A practical method for the synthesis of homochiral 2,10 camphanediols

The esters 3a and 3b are conveniently prepared from (+)-ketopinic acid (7,7-dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylate, 1) and are subsequently reduced to afford exo- and endo-2,10-camphanediols [1-(hydroxymethyl)-7,7-dimethylbicyclo [2.2.1]heptan-2-ols, 4a and 4b, respectively] in good overall yield. The alkylation of ester 3a with buyllithium gives only exo-10,10-dibutyl-2,10-camphanediol [exo-1-(1-butyl-1-hydroxypentyl)-7,7-dimethylbicyclo[2.2.1]heptan-2-ol, 5] in good yield.