129872-12-4

Upstream product

• 123-73-9 trans-Crotonaldehyde 
• 618-36-0 rac-methylbenzylamine 
• 3886-69-9 (R)-1-phenyl-ethyl-amine 

Downstream Products

• 118495-14-0 N-1',3'-butadienyl-N-((R)-(+)-α-methylbenzyl)-2-methyl-2-cyclopentene-1-carboxylic amide 
• 112899-11-3 (1R,4S,8R,11S)-11-methyl-3-<(R)-α-phenethyl>-3-azatricyclo<6.2.1.0^4,11>undec-5-en-2-one 
• 129940-03-0 (1S,4R,8S,11R)-11-methyl-3-<(R)-α-phenethyl>-3-azatricyclo<6.2.1.0^4,11>undec-5-en-2-one 
• 118495-21-9 2-Methyl-cyclopent-2-enecarboxylic acid ((R)-1-phenyl-ethyl)-amide 

Relevant academic research and scientific papers

Applications of Intramolecular Diels-Alder Reactions to Alkaloid Synthesis. A Formal Total Synthesis of (+/-)-Dendrobine

A facile synthesis of the tricyclic enone 3 was completed; since 3 was an intermediate in a previous synthesis of (+/-)-dendrobine (1), this achievement constitutes a formal total synthesis of the racemic title alkaloid.The key strategic element of the ap

Nucleophilic addition to tricarbonyliron(0) complexes of 1-aza-1,3-dienes and the production of pyrroles

The synthesis of a number of novel tricarbonyl(1-aza-1,3-diene)iron(0) complexes and their reactions with methyl-lithium are described. Addition proceeds under mild conditions and, in general, occurs at a metal carbonyl ligand; this leads via an unprecedented reaction to the production of several novel pyrroles.