129915-97-5

Basic information

• Product Name: (3,4-dimethylphenoxo)4TaCl(tetrahydrofuran)
• CAS NO: 129915-97-5
• Molecular Weight: 773.143
• Mol File: 129915-97-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3,4-dimethylphenoxo)4TaCl(tetrahydrofuran)(CAS DataBase Reference)
• NIST Chemistry Reference: (3,4-dimethylphenoxo)4TaCl(tetrahydrofuran)(129915-97-5)
• EPA Substance Registry System: (3,4-dimethylphenoxo)4TaCl(tetrahydrofuran)(129915-97-5)

Safety Data

• Hazardous Substances Data: 129915-97-5(Hazardous Substances Data)

Upstream product

• 7721-01-9 tantalum pentachloride 
• 37622-15-4 sodium 3,4-dimethylphenolate 

Relevant articles and documents

Synthesis, characterisation and adduct formation of (3,4-dimethylphenoxo)tantalum(V) chlorides

New 3,4-dimethylphenoxotantalum(V) chlorides of the type Ta(OC6H3Me2-3,4)xCl5-x (1a-c), (where x = 1,2,3) have been synthesized by the interaction of tantalum(V) chloride and 3,4-dimethylphenol in benzene (or dichloromethane), under refluxing conditions.Treatment of 1a-c with donor ligands such as pyridine (Py) or tetrahydrofuran (THF) yields molecular adducts of the types, Ta(OC6H3Me3-3,4)xCl5-x(Py) (2a-c) and Ta(OC6H3Me2-3,4)xCl5-x (THF) (3a-c) (x = 1,2,3).Interaction of sodium 3,4-dimethylphenolate with TaCl5 in THF and benzene in different stoichiometric ratios yields adducts of the type Ta(OC6H3Me2-3,4)xCl5-x (THF) (3c-e) (x = 3,4,5).These derivatives have been characterized by elemental analyses, IR and PMR spectral data as well as molecular weight determinations.