1300646-27-8

Basic information

• Product Name: [(cyclopentadienyl)2Zr(P⁽¹⁾(SiMe₃)-P⁽²⁾(Ph)2)(P⁽³⁾(SiMe₃)2)]
• CAS NO: 1300646-27-8
• Molecular Weight: 688.116
• Mol File: 1300646-27-8.mol

Chemical Properties

• CAS DataBase Reference: [(cyclopentadienyl)2Zr(P⁽¹⁾(SiMe₃)-P⁽²⁾(Ph)2)(P⁽³⁾(SiMe₃)2)](CAS DataBase Reference)
• NIST Chemistry Reference: [(cyclopentadienyl)2Zr(P⁽¹⁾(SiMe₃)-P⁽²⁾(Ph)2)(P⁽³⁾(SiMe₃)2)](1300646-27-8)
• EPA Substance Registry System: [(cyclopentadienyl)2Zr(P⁽¹⁾(SiMe₃)-P⁽²⁾(Ph)2)(P⁽³⁾(SiMe₃)2)](1300646-27-8)

Safety Data

• Hazardous Substances Data: 1300646-27-8(Hazardous Substances Data)

Upstream product

• 1291-32-3 zirconocene dichloride 
• 1101-41-3 Tetraphenyldiphosphin 

Relevant articles and documents

General route for the synthesis of terminal phosphanylphosphido complexes of Zr(IV) and Hf(IV): Structural investigations of the first zirconium complex with a phosphanylphosphido ligand

Reactions of R2P-P(SiMe3)Li with [Cp 2MCl2] (M = Zr, Hf) in hydrocarbons yield the related terminal phosphanylphosphido complexes [Cp2M(Cl){(Me 3Si)P-PR2-κP1}] (R = iPr and tBu). The solid state structures of [Cp2M(Cl){P(SiMe 3)-PiPr2-κP1}] (M = Zr, Hf) were established by single crystal X-ray diffraction studies. The phosphido-P atoms adopt almost planar geometries and the phosphanyl P atoms adopt pyramidal geometries. The reaction of a mixture of (Me3Si)2PLi and Ph2P-P(SiMe3)Li with [CpZrCl3] in toluene yields the dinuclear complex [Cp2Zr2Cl5(Ph 2PPPSiMe3)(Li THF DME)].