1300734-97-7Relevant academic research and scientific papers
Synthesis, structure, and electronic calculations of group VII substituted pyridazines
Snyder,Tice,Maddox,Young,Mazzotta,Garabato,Evans,Dopierala,Shah,Claytor,Smith
, p. 801 - 809 (2013)
A series of 5,6-fused ring cyclopentadienyl tricarbonyl manganese and rhenium complexes, [M(CO)3{η 5-1,2-C5H 3(1,4-(R)2N2C2}] (2a-3d) were isolated by employing an off-metal ring
Synthesis, characterization, and structure of some new substituted 5,6-fused ring pyridazines
Snyder, Chad A.,Tice, Nathan C.,Sriramula, Phenahas G.,Neathery, James L.,Mobley, Justin K.,Phillips, Chad L.,Preston, Andrew Z.,Strain, Jacob M.,Vanover, Eric S.,Starling, Michael P.,Sahi, Nilesh V.
experimental part, p. 1357 - 1369 (2011/05/11)
Pyridazines are an important class of heterocyclic compounds as a result of their materials and commercial applications. The synthesis of 5,6-fused ring pyridazines 2a-h from 1,2-diacylcyclopentadienes (fulvenes) 1a-h is described herein. This route was quite general, and features an efficient and convenient two-step synthesis of a series of 5,6-fused ring 1,2-disubstituted pyridazines using enolized 1,2-disubstituted fulvenes in a methanolic solution of hydrazine. Full characterization of newly formed fulvene 1e and pyridazines 2a-h are reported. Single-crystal X-ray analysis confirms the molecular structure of pyridazine 2f, which displayed the expected pyridazine fused to the cyclopentadienyl moiety. Adding to their real world capabilities in electronic devices, compounds 2a-h display reasonably high stability in solution and in air at room temperature.
