130102-53-3

Basic information

• Product Name: {Fe(CO)3(P(CH₃)3)(PCH₃(C₆H₅)2)}
• CAS NO: 130102-53-3
• Molecular Weight: 416.176
• Mol File: 130102-53-3.mol

Chemical Properties

• CAS DataBase Reference: {Fe(CO)3(P(CH₃)3)(PCH₃(C₆H₅)2)}(CAS DataBase Reference)
• NIST Chemistry Reference: {Fe(CO)3(P(CH₃)3)(PCH₃(C₆H₅)2)}(130102-53-3)
• EPA Substance Registry System: {Fe(CO)3(P(CH₃)3)(PCH₃(C₆H₅)2)}(130102-53-3)

Safety Data

• Hazardous Substances Data: 130102-53-3(Hazardous Substances Data)

Upstream product

• 1486-28-8 diphenyl(methyl)phosphine 

Relevant articles and documents

Preparation and characterization by 31P-NMR spectroscopy of mixed disubstituted complexes

The disubstituted complexes , where L and L' are different phosphine ligands have been prepared by reaction of the hydrosilyl derivatives with L'.Good results were obtained for L = PMe3 and L' = PPh3, P(OPh)3, P(OEt)3 or P(O-i-Pr)3 but with L' = PMe2Ph, PMePh2, PEt3, a mixture of homo and mixed disubstituted derivatives were obtained.The results can be interpreted in terms of exchange of the L ligand in 3 with L'.The variations in the 31P NMR chemical shifts and 2JPP coupling constants are discussed in the light of the properties of the ligands, and good correlations are revealed with the cone angle and the pKa, respectively.