1301254-14-7Relevant articles and documents
Molecular and spectroscopic properties of chloride and thiocyanate hydridecarbonyl ruthenium(II) complexes with pyridine derivative ligands
Ma?ecki,Maroń
, p. 1225 - 1232 (2011/05/30)
[RuH(CO)(dpa)(PPh3)2]X and [RuHX(CO)(pyCHPh)(PPh 3)2] (X = Cl, NCS) complexes (where dpa = 2,2′-dipyridylamine, pyCHPh = 4-(3-phenylpropyl)pyridine) have been prepared and studied using IR, NMR, UV-Vis spectroscopies and X-ray crystallography. The electronic structures and bonding of the obtained complexes were defined on the basis of the DFT method. The electronic spectra of the complexes were calculated and associated with the structure of the molecular orbitals of the complexes. The luminescence properties of the complexes were determined.