130129-15-6

Basic information

• Product Name: (4S,6R)-6-Benzyloxymethyl-4-methyl-tetrahydro-pyran-2-one
• Synonyms: (4S,6R)-6-Benzyloxymethyl-4-methyl-tetrahydro-pyran-2-one
• CAS NO: 130129-15-6
• Molecular Weight: 234.295
• Mol File: 130129-15-6.mol

Chemical Properties

• CAS DataBase Reference: (4S,6R)-6-Benzyloxymethyl-4-methyl-tetrahydro-pyran-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (4S,6R)-6-Benzyloxymethyl-4-methyl-tetrahydro-pyran-2-one(130129-15-6)
• EPA Substance Registry System: (4S,6R)-6-Benzyloxymethyl-4-methyl-tetrahydro-pyran-2-one(130129-15-6)

Safety Data

• Hazardous Substances Data: 130129-15-6(Hazardous Substances Data)

Upstream product

• 130129-09-8 methyl (R)-5-hydroxyhex-2-ynoate 
• 130625-89-7 (Z)-(R)-6-Benzyloxy-5-hydroxy-hex-2-enoic acid methyl ester 
• 15681-48-8 lithium dimethylcuprate 
• 120996-46-5 (R)-6-Benzyloxymethyl-5,6-dihydro-2-pyrone 
• 917-54-4 methyllithium 

Downstream Products

• 130625-99-9 Toluene-4-sulfonic acid (3R,5R)-6-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-3-methyl-hexyl ester 
• 130626-00-5 ((1R,3R)-1-Benzyloxymethyl-3,7-dimethyl-octyloxy)-tert-butyl-dimethyl-silane 
• 130625-96-6 methyl (3S,5R)-6-benzyloxy-5-t-butyldimethylsiloxy-3-methylhexanoate 
• 130625-98-8 (3R,5R)-6-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-3-methyl-hexan-1-ol 
• 130626-02-7 (2R,4R)-1,2-O-benzylidene-4,8-dimethylnonane-1,2-diol 
• 130626-04-9 Benzoic acid (1R,3R)-1-bromomethyl-3,7-dimethyl-octyl ester 
• 130625-97-7 methyl (3S,5R)-6-benzyloxy-5-hydroxy-3-methylhexanoate 

Relevant articles and documents

Hydroxyl-directed cyclopropanation of Z-allylsilanes

Z-5-Hydroxy-alk-2-enyl-silanes of general structure 1 are cyclopropanated by an excess of CH2l2 / Et2Zn in good yield and excellent stereoselectivity. Ensuing protodesilylation, however, lacks efficient regiocontrol and affords syn-products 5 in modest yield but high stereochemical purity.

New asymmetric synthesis of a pheromone component of the shield bug Cantao Parentum

A novel procedure has been developed for the synthesis of (2S,4R,6R,8S)-2,4,8-trimethyl-1,7-dioxaspiro[5.5]undecane, a pheromone component of the shield bug Cantao Parentum, through intermediate cyclopropanol derivatives in the key stages of carbon chain

A CONVERGENT ENANTIOCONTROLLED ROUTE TO MEVALONOLACTONE AND VITAMIN E FROM (S)-O-BENZYLGLYCIDOL

A convergent enantiocontrolled route to (+) and (-)-mevalonolactones and vitamin E has been developed using (S)-O-benzylglycidol as the sole chiral block.

Enantio-and Stereo-controlled Construction of Tertiary and Quaternary Carbon Centers Using Chiral O-Benzylglycidol as Template

An efficient method for the enantio- and stereo-controlled construction of tertiary and quaternary carbon centers in a highly functionalized system has been developed using chiral O-benzylglycidol as template.