130131-75-8Relevant articles and documents
C-H activation at the 3-position of pentane chains to form [N-C(sp3)-N]- complexes incorporating six-membered pallada(II)cyclic rings and pyridine, pyrazole and N-methylimidazole donor groups. Structural studies and comparison with [
Canty, Allan J.,Patel, Jim,Skelton, Brian W.,White, Allan H.
, p. 194 - 202 (2000)
Alkylpalladium complexes bearing the [N-C(sp3)-N]- donor motif and two six-membered palladacycles are generated on activation of C(sp3)-H bonds by palladium(II) acetate. Cyclopalladation of the new reagents 1,5-bis(pyridin
Poly(pyrazol-1-ylmethyl)benzenes: New Multidentate Ligands
Hartshorn, Chris M.,Steel, Peter J.
, p. 1587 - 1600 (2007/10/03)
Twelve new multidentate poly(pyrazol-1-ylmethyl)benzene ligands, (5)-(16), have benn synthesized by phase-transfer-catalysed alkylations of pyrazoles with poly(bromomethyl)benzenes, and their 1H and 13C n.m.r. spectra have been fully assigned.X-Ray crystal structure determinations have been carried out on the tetrachloropalladate salt of the diprotonated form of 1,4-bis(3,5-dimethylpyrazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene and on hexakis(pyrazol-1-ylmethyl)benzene.
Synthesis and structural studies of tripodal and planar (-) intramolecular coordination systems involving pyrazole donor groups, including oxidative addition of an aryl-bromine bond to platinium(II). Crystal structures of
Canty, Allan J.,Honeyman, R. Thomas,Skelton, Brian W.,White, Allan H.
, p. 277 - 288 (2007/10/02)
The complex 2 undergoes oxidative addition reactions with chloro-2,2-bis(pyrazol-1-yl)propanes and 2,6-(pzCH2)2C6H3Br to form platinum(IV) complexes PtClMe2 and PtBrMe21>, respecti
Canty, Allan J.,Honeyman, R. Thomas,Skelton, Brian W.,White, Allan H.
, p. 277 - 288 (2007/10/02)
The complex 2 undergoes oxidative addition reactions with chloro-2,2-bis(pyrazol-1-yl)propanes and 2,6-(pzCH2)2C6H3Br to form platinum(IV) complexes PtClMe2 and PtBrMe21>, respecti