130138-79-3Relevant articles and documents
REACTION OF PENTAFLUORO-2-AZAPROPENE WITH β,γ-UNSATURATED ALCOHOLS
Andreev, V. G.,Kolomiets, A. F.,Sokol'skii, G. A.
, p. 1493 - 1495 (2007/10/02)
Pentafluoro-2-azapropene reacts vigorously with β,γ-unsaturated alcohols in the presence of bases to give either the corresponding N-trifluoromethylcarbamates or the products of the vinyl substitution of the fluorine atoms at the azomethine bond.The intermediate azanions do not undergo -sigmatropic rearrangement to give perfluoro-2-azapropenyl ethers.