1301750-54-8

Basic information

• Product Name: 4-(tert-butyldimethylsilyloxymethyl)-3-(phenylsulfonyl)pent-4-en-2-ol
• Synonyms: 4-(tert-butyldimethylsilyloxymethyl)-3-(phenylsulfonyl)pent-4-en-2-ol
• CAS NO: 1301750-54-8
• Molecular Weight: 370.585
• Mol File: 1301750-54-8.mol

Chemical Properties

• CAS DataBase Reference: 4-(tert-butyldimethylsilyloxymethyl)-3-(phenylsulfonyl)pent-4-en-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(tert-butyldimethylsilyloxymethyl)-3-(phenylsulfonyl)pent-4-en-2-ol(1301750-54-8)
• EPA Substance Registry System: 4-(tert-butyldimethylsilyloxymethyl)-3-(phenylsulfonyl)pent-4-en-2-ol(1301750-54-8)

Safety Data

• Hazardous Substances Data: 1301750-54-8(Hazardous Substances Data)

Upstream product

• 117037-30-6 3-hydroxy 2-methylene propanesulfonyl benzene 
• 75-07-0 acetaldehyde 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Relevant articles and documents

1,5-Stereocontrol in reactions of 2,4-disubstituted alk-2-enylstannanes with aldehydes; an approach to the stereoselective synthesis of branched triols

2-(tert-Butyldimethylsilyloxymethyl)-4-(methoxymethoxy)pent-2-enyl(tributyl)stannane is transmetallated by tin(IV) chloride stereoselectively to give a pent-1-en-3-yltin trichloride that reacts with aldehydes with excellent (E)-1,5-syn-stereocontrol, e.g.

Stereochemical aspects of the chemistry of 2-[trialkyl(aryl)silyloxy]alkyl- 4-alkoxyalk-2-enylstannanes

2-tert-Butyldimethylsilyloxymethyl-4-(methoxymethoxy)pent-2-enyl(tributyl) stannane, prepared predominantly as the (Z)-isomer, is transmetallated by tin(IV) chloride to generate an allyltin trichloride which reacts with aldehydes with excellent stereocont