130193-64-5Relevant academic research and scientific papers
Stereoselective catalytic double osmylation of 1,2-dihydropyridines leading to amino-arabinose and to amino-altrose derivatives and to potential glycosidase inhibitors
Tschamber, Theophile,Backenstrass, Frederique,Neuburger, Marcus,Zehnder, Margareta,Strieth, Jacques
, p. 1135 - 1152 (1994)
Catalytic double osmylation of 1,2-dihydropyridines 1b and 1c proceeded stereospecifically and in good yields to the corresponding aminoarabinose 2b, and aminoaltrose 2c derivatives, respectively. In basic medium these piperidinoses equilibrated with thei
Stereospecific double glycolisation of 1,2-dihydropyridines with OsO4. Synthesis of (±) aminoarabinose- and of (±) aminoaltrose derivatives [1]
Backenstrass, Frededrique,Streith, Jacques,Tschamber, Theophile
, p. 2139 - 2142 (2007/10/02)
Double glycolisation of 1,2-dihydropyridines 1 led stereospecifically and in good yield to the corresponding (±) aminoarabinose- and (±) aminoaltrose derivatives 5. Hydrogenolysis of the N-benzyloxy carbonyl piperidinose 5b gave directly the 1-desoxy derivative 7a.
