130195-91-4

Basic information

• Product Name: 6-Oxabicyclo[3.1.0]hex-3-en-2-one, 1-(methoxymethyl)-, (1R)- (9CI)
• Synonyms: 6-Oxabicyclo[3.1.0]hex-3-en-2-one, 1-(methoxymethyl)-, (1R)- (9CI)
• CAS NO: 130195-91-4
• Molecular Formula: C₇H₈O₃
• Molecular Weight: 140.14
• Mol File: 130195-91-4.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 6-Oxabicyclo[3.1.0]hex-3-en-2-one, 1-(methoxymethyl)-, (1R)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 6-Oxabicyclo[3.1.0]hex-3-en-2-one, 1-(methoxymethyl)-, (1R)- (9CI)(130195-91-4)
• EPA Substance Registry System: 6-Oxabicyclo[3.1.0]hex-3-en-2-one, 1-(methoxymethyl)-, (1R)- (9CI)(130195-91-4)

Safety Data

• Hazardous Substances Data: 130195-91-4(Hazardous Substances Data)

Upstream product

• 127588-16-3 5-Ethoxy-4-(-)-menthyloxymethyl-exo-10-oxatricyclo<5.2.1.0^2,6>deca-4,8-dien-3-one 
• 130195-90-3 (1S,2R,6S,7R)-4-Methoxymethyl-10-oxa-tricyclo[5.2.1.0^2,6]deca-4,8-dien-3-one 
• 112698-62-1 (-)-exo-4,5-Epoxy-endo-4-methoxymethyl-exo-10-oxatricyclo<5.2.1.0^2,6>deca-8-en-3-one 
• 112698-50-7 5-hydroxy-4-(p-tolylsulphonyl)methyl-exo-10-oxatricyclo<5.2.1.0^2,6>deca-4,8-dien-3-one 
• 112698-51-8 5-ethoxy-4-methoxymethyl-exo-10-oxa-tricyclo<5.2.1.0^2,6>deca-4,8-dien-3-one 
• 62926-69-6 5-hydroxy-exo-10-oxatricyclo<5.2.1.0^2,6>deca-4,8-dien-3-one 
• 112698-71-2 5-ethoxy-4-(p-tolylsulphonyl)methyl-exo-10-oxatricyclo<5.2.1.0^2,6>deca-4,8-dien-3-one 
• 112723-14-5 4-methoxymethyl-exo-10-oxatricyclo<5.2.1.0^2,6>deca-4,8-dien-3-one 
• 112698-62-1 exo-4,5-epoxy-endo-4-methoxymethyl-exo-oxatricyclo<5.2.1.0^2,6>deca-8-en-3-one 

Downstream Products

• 129076-61-5 (4S^*,5R^*)-5-(3,5-Dinitrophenylcarbonyloxy)-4-methoxy-5-methoxymethyl-2-cyclopentenone 

Relevant articles and documents

Menthol mediated optical resolution of 10-oxatricyclodecadienones. Application in the enantioselective synthesis of cyclopentenoids

The efficient conversion of 5-ethoxy-4-p-tolylsulphonylmhetyl-exo-10-oxatricyclo[5.2.1.0 2,6]deca-4,8-dien-3-one 6 into a diastereomeric mixture of the (-)menthyl ethers, 9a and 9b, is described. Separation of these ethers, followed by reductio

SULFONE MEDIATED SYNTHESIS OF CYCLOPENTADIENONE EPOXIDES FROM 10-OXATRICYCLO /5.2.1.02,6/ DECADIENONES . A CONVENIENT ROUTE TO epi-PENTENOMYCINS

Sulfonylmethylation of 10-oxatricyclodecadienone 6 leads to sulfone 4 which forms the key intermediate in the synthesis of 5-alkoxymethylcyclopentadienone epoxides 5.Acid catalyzed hydrolysis of 5 followed by acylation affords epi-pentenomycin derivates 1