130236-40-7

Upstream product

• 71655-17-9 (E)-3-hexen-1,6-diol 
• 29311-53-3 (E)-3-hexene-1,6-dioic acid 
• 110-87-2 3,4-dihydro-2H-pyran 
• 88730-60-3 (E)-6-(tetrahydro-2H-pyran-2-yloxy)hex-3-en-1-ol 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 130236-43-0 (E)-6-(2-tetrahydropyranyloxy)-hex-3-enyltriphenyl phosphonium iodide 
• 19926-63-7 3,6,8-dodecatrien-1-ol 
• 19926-63-7 3,6,8-dodecatrien-1-ol 
• 1578145-50-2 (E)-2-(4-nitrophenyl)-4,5,8,9-tetrahydro-1,3-oxathionine 

Relevant academic research and scientific papers

Tuning the reactivity of oxygen/sulfur by acidity of the catalyst in Prins cyclization: Oxa-versus thia-selectivity

An unprecedented oxa- versus thia-selectivity has been observed in Prins cyclization of 6-mercaptohex-3-en-1-ol with aldehydes. In the presence of a stoichiometric amount of strong Lewis or Bronsted acids, the reaction provides the hexahydro-2H-thieno[3,2

Syntheses and NMR analyses of the eight geometric isomers of 3,6,8-dodecatrien-1-ol, subterranean termite trail pheromone

Eight geometric isomers of 3,6,8-dodecatrien-1-ol 1, the trail-following pheromone of subterranean termites (Reticulitermes sp. Banks), were synthesized via a Wittig olefination reaction. The convergent syntheses of 1 consisted of a combination of two fragments, each containing an olefin with a fixed configuration, by formation of a third double bond to give a mixture of two geometric isomers. The mixtures of 1 were resolved by recycle high-performance liquid chromatography methods. 1H and 13C NMR peak assignments of the individual isomers were accomplished by homonuclear COSY, and one-bond CH correlation spectroscopy.