130246-97-8Relevant academic research and scientific papers
P-C Bond Activation and η4-Coordination of Arene: X-ray Crystal Structure of a Dinuclear μ-Phosphido μ-η2:η2-Phenoxo Zwitterionic Complex of Palladium Trapping an Aggregate of Three Hydrogen-Bonded Phenol Molecules
Sommovigo, Milena,Pasquali, Marco,Leoni, Piero,Braga, Dario,Sabatino, Piera
, p. 97 - 99 (2007/10/02)
Pd2 reacts photochemically with an excess of phenol in n-hexane to give the dinuclear complex 2Pd2(μ-η2:η2-C6H5O)>*3C6H5OH (1); X-ray crystallography shows a linear chain of three phenol molecules hydrogen-bonded to the phenoxide ligand which is η4-coordinated to the Pd2 framework.The ? coordination of the phenoxide ring is retained in solution, as evidenced by 1H-NMR spectroscopy.
