130247-99-3

Upstream product

• 90719-32-7 (S)-4-Benzyl-2-oxazolidinone 
• 108-98-5 thiophenol 
• 148081-11-2 1-[4-benzyl-2-oxo-(4S)-1,3-oxazolidin-3-yl]-2-methyl-2-propen-1-one 

Downstream Products

• 556834-69-6 methyl 5-(tert-butyldiphenylsilyloxy)-6-methyl-7-phenylsulfinyl-(E,5S,6S)-2-heptenoate 
• 556834-67-4 methyl 3-(tert-butyldiphenylsilyloxy)-4-methyl-5-phenylsulfinyl-(3S,4S)-pentanoate 
• 556834-68-5 (3S,4S)-5-Benzenesulfinyl-3-(tert-butyl-diphenyl-silanyloxy)-4-methyl-pentanal 
• 556834-64-1 (2R,3R,4S)-5-Benzenesulfonyl-2-bromo-4-methyl-pentane-1,3-diol 
• 556834-62-9 methyl 2-bromo-3-hydroxy-4-methyl-5-phenylsulfinyl-(2S,3R,4S)-pentanoate 
• 556834-66-3 methyl 3-hydroxy-4-methyl-5-phenylsulfinyl-(3S,4S)-pentanoate 
• 556834-61-8 methyl 4-methyl-5-phenylsulfinyl-(Z,4S)-2-pentenoate 
• 688364-58-1 methyl 4-methyl-5-phenylsulfanyl-(E,4S)-2-pentenoate 
• 556834-58-3 methyl 4-methyl-5-phenylsulfanyl-(Z,4S)-2-pentenoate 
• 556834-59-4 4-methyl-5-phenylsulfanyl-(Z,4S)-2-penten-1-ol 
• 121783-49-1 (S)-(+)-2-methyl-3-(phenylthio)propan-1-ol 

Relevant academic research and scientific papers

Sulfinyl moiety as an internal nucleophile. 1. Efficient stereoselective synthesis of fragment A of cryptophycin 3

A novel, efficient, and stereoselective synthesis of fragment A of cryptophycin 3 is disclosed. The key step involves the regio- and stereoselective transformation of an unsaturated ester to a bromohydrin via anchimeric assistance by the sulfinyl group.