130248-71-4Relevant academic research and scientific papers
Borane-induced radical reduction of 1-alkenyl- and 1-alkynyl-λ3-iodanes with tetrahydrofuran
Ochiai, Masahito,Tsuchimoto, Yoshimi,Hayashi, Takanori
, p. 5381 - 5384 (2007/10/03)
Exposure of 1-alkenyl(phenyl)- and 1-alkynyl(phenyl)-λ3-iodanes to THF at room temperature in the presence of a catalytic amount of trialkylborane results in smooth reduction to give 1-iodo-1-alkenes and 1-iodo-1-alkynes as major products, respectively. The key step in the reductions probably involves a single-electron transfer from α-tetrahydrofuryl radical to the λ3-iodanes, which generates the labile [9-I-2] iodanyl radicals.
A new synthesis of substituted fulvenes
Lee, Gary C. M.,Tobias, Brian,Holmes, Judy M.,Harcourt, Dale A.,Garst, Michael E.
, p. 9330 - 9336 (2007/10/02)
A new fulvene synthesis results from the palladium-catalyzed [2 + 2 + 2] annulation of 1 mol of a β-substituted vinyl iodide and 2 mol of a monosubstituted acetylene. This variant of the Heck reaction tolerates a wide range of substrate substituents with
