130256-53-0

Upstream product

• 873-55-2 sodium benzenesulfonate 
• 130239-36-0 3-bromo-2-acetoxymethylpropene 
• 106023-64-7 3-bromo-2-(bromomethyl)propyl acetate 

Downstream Products

• 182312-61-4 Acetic acid 4-((1R,2S,4R,5R,6R)-5-hydroxy-2-methoxy-3,7-dioxa-bicyclo[4.1.0]hept-4-yl)-2-methylene-butyl ester 

Relevant academic research and scientific papers

C-allylation of 1- and 6-bromosugars with allylic sulfides and sulfones

Reaction of the bromosugars 2,3,4,6-tetra-O-acetyl-α-D-galactopyranosyl bromide (1), methyl 2,3-anhydro-6-bromo-6-deoxy-α-D-allopyranoside (2), and methyl 2,3-anhydro-4-O-benzoyl-6-bromo-6-deoxy-α-D-allopyranoside (3) with the allylic sulfides and sulfones 4-9 in the presence of hexabutyldistannane under photolytic conditions gave the corresponding α-C-allyl galactosides 10-12 and the 6-C-allylated epoxysugars 13, 15, and 16 in 61-90% yield.

2-Bromomethylprop-2-en-1-yl Acetate; Synthesis and Applications

Fluoride-ion-mediated elimination of hydrogen bromide from 3-bromo-2-bromomethylpropyl acetate gave the title compound, the bromine atom of which was specifically substituted by various nucleophiles to yield the corresponding phenyl sulphone, dimethyl mal