13031-10-2

Basic information

• Product Name: 2,2-Dimethyl-1,3-diphenyl-1-propanol
• Synonyms: 2,2-Dimethyl-1,3-diphenyl-1-propanol
• CAS NO: 13031-10-2
• Molecular Weight: 240.345
• Mol File: 13031-10-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,2-Dimethyl-1,3-diphenyl-1-propanol(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2-Dimethyl-1,3-diphenyl-1-propanol(13031-10-2)
• EPA Substance Registry System: 2,2-Dimethyl-1,3-diphenyl-1-propanol(13031-10-2)

Safety Data

• Hazardous Substances Data: 13031-10-2(Hazardous Substances Data)

Upstream product

• 1009-62-7 2,2-dimethyl-3-phenylpropionaldehyde 
• 6843-66-9 dimethoxy(diphenyl)silane 
• 64-17-5 ethanol 
• 13031-08-8 4-phenylpivalophenone 

Downstream Products

• 13031-08-8 4-phenylpivalophenone 
• 80607-60-9 N-Butyl-3,3-dimethyl-2,4-diphenylbutyramid 
• 80607-78-9 3,3-Dimethyl-2,4-diphenyl-butyryl chloride 
• 345221-44-5 3,3-Dimethyl-2,4-diphenylbuttersaeure 
• 57015-18-6 1-(1-benzyl-2-methyl-1-propenyl)benzene 
• 80607-85-8 1-chloro-2,2-dimethyl-1,3-diphenyl-propane 

Relevant articles and documents

Palladium-catalyzed asymmetric hydrogenation of simple ketones activated by Br?nsted acids

Homogeneous Pd(OCOCF3)2/(R)-C4-TunePhos has been successfully applied in the asymmetric hydrogenation of simple ketones activated by catalytic amount of Br?nsted acid with up to 88% ee.

Stereoisomerization of Ketene Imines

Barriers to racemization in solution of the ketene imines 1a - y and X-ray structures of the ketene imines 1s and z are described.Similar to allenes all ketene imines have dihedral angles of 90 deg between the C- and N-substituents.The barriers to racemization range from 30 to 63 kJmol-1 and are lowered by electron attracting substituents on C and N.The barriers of m- and p-substituted N-arylketene imines give a linear Hammett correlation with ?- constants.N-Arylketene imines racemize through inversion at nitrogen and simultaneous rotation of the aryl group around the N - aryl bond.