130323-28-3

Upstream product

• 81445-44-5 (S)-2-(benzyloxy)propanal 
• 115-11-7 isobutene 
• 17963-05-2 (2-methyl-2-propenyl)triethoxysilane 
• 81927-55-1 O-benzyl 2,2,2-trichloroacetimidate 
• 54783-72-1 ethyl (S)-2-(benzyloxy)propionate 

Downstream Products

• 1352481-41-4 (4R,6S)-4-((2S,3S)-3-(benzyloxy)-2-(4-methoxybenzyloxy)butyl)-6-(2-(5-((tertbutyldimethylsilyloxy)methyl)furan-2-yl)propan-2-yl)-2,2-diisopropyl-1,3,2-dioxasilinane 
• 1352481-42-5 5-(2-((4S,6R)-6-((2S,3S)-3-(benzyloxy)-2-hydroxybutyl)-2,2-diisopropyl-1,3,2-dioxasilinan-4-yl)propan-2-yl)furan-2-carbaldehyde 
• 1352481-43-6 (E)-((2S,3S)-3-(benzyloxy)-1-((4R,6S)-6-(2-(5-formylfuran-2-yl)propan-2-yl)-2,2-diisopropyl-1,3,2-dioxasilinan-4-yl)butan-2-yl) but-2-enoate 
• 1352481-44-7 C₃₂H₄₆O₇Si 
• 1352481-46-9 C₃₂H₄₈O₇Si 
• 1352481-47-0 C₃₂H₄₆O₇Si 
• 1352481-48-1 C₃₂H₄₈O₇Si 
• 1352481-49-2 C₃₈H₆₀O₇Si₂ 
• 1352481-50-5 C₃₈H₆₂O₉Si₂ 
• 1352481-51-6 C₄₄H₇₆O₉Si₃ 
• 1352481-52-7 C₄₅H₇₈O₉Si₃ 
• 1352481-53-8 C₃₉H₆₄O₉Si₂ 
• 1352481-54-9 C₃₉H₆₄O₁₀Si₂ 
• 1365414-38-5 C₄₄H₇₂O₇Si₂ 

Relevant academic research and scientific papers

Toward the synthesis of (+)-peloruside A via an intramolecular vinylogous aldol reaction

The use of the intramolecular vinylogous aldol reaction for the preparation of an advanced intermediate for the synthesis of peloruside A is described. The reaction was applied to compound 19 and proceeds in high yield and good levels of diastereoselectiv

Allylcopper intermediates with N-heterocyclic carbene ligands: Synthesis, structure, and catalysis

(Figure presented) Allylcopper Intermediates with N-heterocyclic carbene liganda are synthesized by transmetalation of allylsiloxane reagents, and the crystal structures of allylcopper compounds are reported. The allylcopper transmetalation is utilized fo

Asymmetric Carbonyl Addition Reactions to Benzyloxyaldehydes by Binaphthol-Titanium Catalyst: Anti- vs. Syn-Diastereofacial Preference in Anomalous Nonchelation Complexation

An anomalous nonchelation diastereofacial selectivity is observed in the titanium-catalyzed carbonyl addition reaction to benzyl-protected alkoxyaldehydes.There is a dichotomy in the sense of syn- vs. anti-diastereofacial preference, dictated by the bulkiness of the migratory group: The sterically demanding silyl group gives syn-diastereofacial preference and the less sterically demanding proton leads to anti-diastereofacial preference.

Acyclic Stereocontrol Based on Chelation-Controlled Ene Reaction with Chiral α- and β-Alkoxyaldehydes

The Lewis acid-promoted ene reactions with chiral α- and β-benzyloxyaldehydes have been developed and shown to afford high levels of both diastereofacial (chelation) selection and simple diastereoselection (anti), thus providing an efficient method for stereocontrol over three contiguous chiral centers.