1303459-35-9Relevant academic research and scientific papers
Rhodium-catalyzed oxidative alkynylation of acrylate esters with propargylic alcohols
Nishimura, Takahiro,Nagaosa, Makoto,Hayashi, Tamio
, p. 2185 - 2187 (2011)
Oxidative alkynylation of acrylate esters with propargylic alcohols giving conjugated enyne esters was realized by use of a diene-rhodium catalyst. Propargylic alcohols were found to be useful alkynylating reagents in the present reaction to produce alkynylrhodium species via carbon-carbon bond cleavage. An excess of the acrylate ester worked as a hydride acceptor to reproduce the active rhodium species.
