13035-03-5Relevant articles and documents
Synthesis of cyclic peroxides containing the Si-gem-bisperoxide fragment. 1,2,4,5,7,8-hexaoxa-3-silonanes as a new class of peroxides
Terent'ev, Alexander O.,Platonov, Maxim M.,Tursina, Anna I.,Chernyshev, Vladimir V.,Nikishin, Gennady I.
, p. 3169 - 3174 (2008/09/19)
(Chemical Equation Presented) A method was developed for the synthesis of the previously unknown class of organic peroxides, 1,2,4,5,7,8-hexaoxa-3- silonanes, based on the reaction of dialkyldichlorosilanes with 1,1′-dihydroperoxyperoxides. 1,2,4,5,7,8-Hexaoxa-3-silonanes are rather stable under ambient conditions and were characterized by NMR spectroscopy, X-ray diffraction, and elemental analysis. Their yields are in a range of 59-96%. The attempts were made to prepare 1,2,4,5-tetraoxa-3-silinanes by the reaction of dialkyldichlorosilanes with gem-bishydroperoxides. 1,2,4,5-Tetraoxa-3-silinanes were detected by NMR spectroscopy; these compounds rapidly decompose upon isolation.
