130359-45-4

Basic information

• Product Name: methyl 2-O-acetyl-6-O-tert-butyldiphenylsilyl-α-D-glucopyranoside
• Synonyms: methyl 2-O-acetyl-6-O-tert-butyldiphenylsilyl-α-D-glucopyranoside
• CAS NO: 130359-45-4
• Molecular Weight: 474.626
• Mol File: 130359-45-4.mol

Chemical Properties

• CAS DataBase Reference: methyl 2-O-acetyl-6-O-tert-butyldiphenylsilyl-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-O-acetyl-6-O-tert-butyldiphenylsilyl-α-D-glucopyranoside(130359-45-4)
• EPA Substance Registry System: methyl 2-O-acetyl-6-O-tert-butyldiphenylsilyl-α-D-glucopyranoside(130359-45-4)

Safety Data

• Hazardous Substances Data: 130359-45-4(Hazardous Substances Data)

Upstream product

• 58479-62-2 (2R,3S,4S,5R,6S)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-6-methoxy-tetrahydro-pyran-3,4,5-triol 
• 108-24-7 acetic anhydride 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Relevant articles and documents

Directing-protecting groups for carbohydrates. Design, conformational study, synthesis and application to regioselective functionalization

A novel concept of regioselective transformation of secondary hydroxyl groups in carbohydrates is presented. First, the relative reactivity of the free hydroxyl groups of onoprotected d-glucose derivatives was assessed using acetylation as a model reactio

Novel methods for the preparation of partially acetylated carbohydrates

The selective acetylation of methyl α-D-hexopyranosides in the presence of zinc chloride shows unusual reactivity patterns compared to control experiments.Hydroperoxide ion is a mild and selective deacetylation reagent which does not attack primary acetates.